Weird - Windows probably won't let you mark the partition active as (for some insatiably stupid reason) it will only let you change markings on partitions it can recognize.
I have not explored the possibility of Grub and OpenBSD, but I highly suggest you look into it. I currently have a Debian-testing and OpenBSD 4.5 dual-boot, in which Grub is my main bootloader, which then chainloads to OpenBSD.
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